کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
69101 48530 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Chiral lanthanum–lithium–binaphthol complex covalently bonded to silica and MCM-41 for enantioselective nitroaldol (Henry) reaction
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Chiral lanthanum–lithium–binaphthol complex covalently bonded to silica and MCM-41 for enantioselective nitroaldol (Henry) reaction
چکیده انگلیسی

A chiral BINOL ligand covalently anchored on silica and mesoporous MCM-41 was synthesized and characterized by powder XRD, FT-IR, N2 adsorption–desorption measurements, TGA and elemental analysis. These anchored ligands were then used to prepare La–Li–BINOL–silica 1a and La–Li–BINOL–MCM-41 1b complexes. The immobilized catalysts having lanthanum content around 0.12–0.18 mmol/g were tested as enantioselective catalyst for Henry reaction and ee 55–84% were found which were comparable to its homogeneous counterpart. The solid catalysts can be reused by simple filtration and recycled several times without much loss in performance.

Chiral BINOL ligand based lanthanum complex supported on Silica and MCM-41 were investigated for enantioselective Henry reaction which gave yield up to 87% of β-hydroxy-nitroalkanes with ee, as high as 84% and the system could be recycled several times without much loss in its performance. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 244, Issues 1–2, 1 February 2006, Pages 110–117
نویسندگان
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