کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6970450 1453046 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermodynamic analysis of Cr(VI) extraction using TOPO impregnated membranes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
Thermodynamic analysis of Cr(VI) extraction using TOPO impregnated membranes
چکیده انگلیسی
Solid/liquid extraction of Cr(VI) was accomplished using trioctylphosphine oxide impregnated polypropylene hollow fiber membranes. Extraction of 100-500 mg/L Cr(VI) by the extractant impregnated membranes (EIM) was characterized by high uptake rate and capacity, and equilibrium was attained within 45 min of contact. Extraction equilibrium was pH-dependent (at an optimal pH 2), whereas stripping using 0.2 M sodium hydroxide yielded the highest recovery of 98% within 60 min. The distribution coefficient was independent of initial Cr(VI) concentration, and the linear distribution equilibrium isotherm could be modeled using Freundlich isotherm. The mass transfer kinetics of Cr(VI) was examined using pseudo-second-order and intraparticle diffusion models and a mass transfer mechanism was deduced. The distribution coefficient increased with temperature, which indicated endothermic nature of the reaction. Enthalpy and entropy change during Cr(VI) extraction were positive and varied in the range of 37-49 kJ/mol and 114-155 J/mol, respectively. The free energy change was negative, confirming the feasibility and spontaneity of the mass transfer process. Results obtained suggest that EIMs are efficient and sustainable for extraction of Cr(VI) from wastewater.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 314, 15 August 2016, Pages 204-210
نویسندگان
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