کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6972694 1453142 2011 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Boron removal and recovery from concentrated wastewater using a microwave hydrothermal method
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
Boron removal and recovery from concentrated wastewater using a microwave hydrothermal method
چکیده انگلیسی
Boron compounds are widely-used raw materials in industries. However, elevated boron concentrations in aqueous systems may be harmful to human and plants. In this study, calcium hydroxide (Ca(OH)2) alone and Ca(OH)2 with phosphoric acid (H3PO4) addition (P-addition) were used to remove and recover boron from wastewater using hydrothermal methods. A microwave (MW) hydrothermal method was used and compared with the conventional heating (CH) method in batch experiments. Physicochemical properties of the precipitates obtained from both methods were analysed by XRD, SEM with EDX and BET. For the case of Ca(OH)2 alone and the MW method, experimental results showed that boron recovery efficiency reached 90% within 10 min, and crystals of Ca2B2O5·H2O were found in the precipitates as indicated by the XRD analysis. For the case of P-addition and the MW method, boron recovery efficiency reached 99% within 10 min, and calcium phosphate species (CaHPO4·H2O, CaHPO4 and Ca10(PO4)6(OH)2) were formed. The experimental results of this study indicate that the required reaction time of the MW method was much less than that of the CH method, and the MW method is an effective and efficient method for boron removal and recovery from concentrated wastewater.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 186, Issues 2–3, 28 February 2011, Pages 1431-1437
نویسندگان
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