کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6980017 | 1453960 | 2012 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Simulation of common features and differences of surfactant-based and solid-stabilized emulsions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
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چکیده انگلیسی
A continuum model is used to study thermodynamical stability of surfactant-based and solid-stabilized emulsions. Both modeling approaches are based on a phase-field description. In the case of solid particles along the fluid-fluid interface a local approximation to a classical dynamic density functional theory is used to account for particle-particle interactions. This allows for attractive as well as repulsive interactions. Coarsening studies are performed, which demonstrate thermodynamic stability for both cases. For surfactant-based emulsions this is achieved by a drastic reduction of surface tension, whereas for solid-stabilized emulsions the same effect results from an elastic force. Both types of emulsions behave different if a macroscopic force is applied. This is demonstrated by a rigid body interacting with the emulsion. The surfactant-based emulsion behaves like a fluid, whereas the solid-stabilized emulsion shows properties of a solid with a finite elastic modulus and a yield stress.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 413, 5 November 2012, Pages 298-302
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 413, 5 November 2012, Pages 298-302
نویسندگان
Sebastian Aland, Axel Voigt,