کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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701074 | 1460815 | 2009 | 5 صفحه PDF | دانلود رایگان |

Diamond-like carbon films were synthesized under atmospheric pressure (AP-DLC) and their gas barrier properties and hardness were measured. The AP-DLC films were uniformly obtained by RF-plasma CVD method at room temperature with a size of 450 mm2. The growth rate increased as a function of C2H2 concentration and the average growth rate was around 12 μm/min. The maximum deposition rate was ~ 1 μm/s, which is approximately 2000 times larger than that by low-pressure plasma CVD of 1–2 μm/h. The gas barrier properties of AP-DLC films, ~ 1 μm thick, were 5–10 times larger than those of uncoated PET substrates. The microhardness of AP-DLC films was around 3 GPa, measured by the nano-indentation method. The issue lies in the removal of macro-particles of the films to improve the microhardness and the surface roughness.In this paper, we report the physical properties of DLC films synthesized under atmospheric pressure by the radio-frequency CVD method. We also summarize a brief history of PET bottle coating by vacuum-DLC films, as well as that of the development of atmospheric pressure technology and related DLC films, focused on gas barrier properties and micro-hardness.
Journal: Diamond and Related Materials - Volume 18, Issues 5–8, May–August 2009, Pages 990–994