کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7077094 | 1459977 | 2014 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Multi-Gaussian-DAEM-reaction model for thermal decompositions of cellulose, hemicellulose and lignin: Comparison of N2 and CO2 atmosphere
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تکنولوژی و شیمی فرآیندی
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چکیده انگلیسی
Thermal decompositions of three components of biomass (cellulose, hemicellulose and lignin) were studied using nonisothermal thermogravimetric analysis (TGA) under both oxidative and inert atmospheres at a heating rate of 10Â KÂ minâ1. The multi-Gaussian-distributed activation energy model (DAEM)-reaction model was first developed to describe thermal decomposition behaviors of three components. Results showed that the presence of CO2 enhanced the thermal decompositions of three components in high temperature range, but made little difference in low temperature range. Decomposition behaviors under CO2 were analyzed by the two-stage reaction mechanism corresponding to the pyrolysis process of original materials and the gasification process of char. During gasification stage, CO2 was reduced to CO, which provided a possibility of a reduction in greenhouse gas emissions. In addition, more CO was produced, and therefore the thermal value of gas was improved. The findings imply that CO2 gasification technology of biomass has great research significance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Bioresource Technology - Volume 166, August 2014, Pages 87-95
Journal: Bioresource Technology - Volume 166, August 2014, Pages 87-95
نویسندگان
Jinzhi Zhang, Tianju Chen, Jingli Wu, Jinhu Wu,