کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7117647 | 1461365 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
In-situ loading of (BiO)2CO3 on g-C3N4 with promoted solar-driven photocatalytic performance originated from a direct Z-scheme mechanism
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موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی برق و الکترونیک
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چکیده انگلیسی
The photocatalytic performance of g-C3N4 has been significantly hindered by its inherent drawbacks; therefore it is highly desirable to ameliorate the photocatalytic performance of g-C3N4. Construction of effective direct Z-scheme photocatalysts is facile approach to boost the separation and transfer of charge pairs, remarkably promoting the photocatalytic performance of the catalysts. Herein, (BiO)2CO3/g-C3N4 heterojunctions with improved solar-driven photocatalytic performance were in-situ constructed by loading (BiO)2CO3 onto the surface of g-C3N4 via a hydrothermal route. The (BiO)2CO3/g-C3N4 heterojunctions were optimized by adjusting the molar ratio between two components. The resulting heterojunctions display much higher photocatalytic activities for rhodamine B (RhB) degradation compared to the pristine g-C3N4 and the 1.5% sample exhibits the highest photocatalytic activity. Based on the surface photovoltage spectroscopy (SPS), the enhanced photocatalytic performance of (BiO)2CO3/g-C3N4 catalysts can be definitely assigned to the significantly promoted charge transfer and separation. The results confirm that the photoinduced charge separation of (BiO)2CO3/g-C3N4 composites obeys a direct Z-scheme mechanism, proven by the results of electron spin-resonance (ESR) and band edge potential.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Science in Semiconductor Processing - Volume 82, 1 August 2018, Pages 97-103
Journal: Materials Science in Semiconductor Processing - Volume 82, 1 August 2018, Pages 97-103
نویسندگان
Jiao Huang, Huanhuan Liu, Jiufu Chen, Junbo Zhong, Jianzhang Li, Ran Duan,