کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7118834 1461406 2015 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Sulfur stoichiometry driven chalcopyrite and pyrite structure of spray pyrolyzed Cu-alloyed FeS2 thin films
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی برق و الکترونیک
پیش نمایش صفحه اول مقاله
Sulfur stoichiometry driven chalcopyrite and pyrite structure of spray pyrolyzed Cu-alloyed FeS2 thin films
چکیده انگلیسی
We report on fabrication of CuxFe1−xS2 (CFS) thin films using chemical spray pyrolysis followed by post-sulfurization. Post-sulfurized CFS films were grown with compact and good crystalline texture. The sulfur stoichiometry in CFS films was found to be crucial for determination of its crystal structure. The sulfur deficient CFS films were driven to chalcopyrite CFS (CH-CFS) structure whereas the sulfur cured CFS films were grown with Cu-incorporated pyrite CFS (P-CFS) structure which was confirmed by X-ray diffraction and Raman spectroscopy analysis along with UV-vis spectroscopy measurement. Electrical characterizations of both types of CFS films revealed p-type conductivity with carrier concentration in the range of 1018-1020 cm−3 and mobility of 0.5-9 cm2 V−1 s−1. The band gaps of CFS films of CH-CFS structure (0.885-0.949 eV) were found to be less than that of P-CFS structure (0.966-1.156 eV), which indicates its potential application for thermoelectric and photovoltaic devices.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Science in Semiconductor Processing - Volume 40, December 2015, Pages 325-330
نویسندگان
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