کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
72977 49039 2014 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Adsorption of dyes with different molecular properties on activated carbons prepared from lignocellulosic wastes by Taguchi method
ترجمه فارسی عنوان
جذب رنگ با خواص مولکولی مختلف بر روی کربن فعال تهیه شده از ضایعات لیگنوسلولزی بوسیله روش تاگوچی
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


• Activated carbons from different lignocellulosic residues with optimum properties were prepared by Taguchi method.
• The optimum carbons had a high specific surface area with a considerable amount of micropores.
• The removal of food and textile dyes was studied and the adsorption behavior was interpreted using molecular tools.

A design of experiments based in the Taguchi method was used to prepare activated carbons from different lignocellulosic residues with optimum properties for the removal of food and textile dyes (food yellow 4, food yellow 3, food red 17 and acid blue 74). A Taguchi L16 orthogonal array was devised for the design of experiments, using the dye removal percentage as response variable and several experimental factors, including the origin of the lignocellulosic precursor, type of chemical agent used for the impregnation of the precursors and other specific variables of the impregnation and thermal treatments. Statistical analysis of the results helped to identify the chemical agent and the final temperature of carbonization/activation as the experimental factors having the most relevant effect on the response (i.e., amount of dye adsorbed). Carbons obtained using the optimum conditions predicted by the Taguchi methodology for each dye were characterized using elemental analysis, FT-IR spectroscopy, adsorption isotherms of nitrogen at −196 °C and SEM/EDX analysis. The optimum carbons had a high specific surface area (∼1400 m2/g) with a considerable amount of micropores (∼50%). Mesoporosity seemed also to play an important role in the adsorption of these dyes.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 199, 15 November 2014, Pages 99–107
نویسندگان
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