کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
73119 49044 2014 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A CVD route for the preparation of templated and activated carbons for gas storage applications using zeolitic imidazolate frameworks (ZIFs) as template
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
A CVD route for the preparation of templated and activated carbons for gas storage applications using zeolitic imidazolate frameworks (ZIFs) as template
چکیده انگلیسی


• High yield of highly microporous ZIF-templated carbons are prepared via a CVD route.
• Templated carbon obtained directly after CVD; no need for washing to etch out ZIF framework.
• Surface area of activated templated carbon up to 2400 m2/g with 82% from micropores.
• Activated ZIF templated carbons store up to 6.2 wt% H2 at −196 °C and 20 bar.
• CO2 uptake up to 2.4 mmol/g (at 25 °C and 1 bar) and exceptional storage density up to 4.5 μmol/m2.

Templated porous carbon materials were prepared via a chemical vapour deposition (CVD) method using zeolitic imidazolate framework (ZIF) templates impregnated with furfuryl alcohol (FA). ZIF-templated carbons prepared at CVD temperature of between 700 and 850 °C are highly microporous and exhibit surface area in the 350–970 m2/g range (with up to 96% from micropores) and pore volume of between 0.28 and 0.66 cm3/g. After chemical activation (with KOH) the surface area and pore volume increase significantly to as high as 2400 m2/g and 1.6 cm3/g, respectively. This increase in porosity is accompanied by a broadening of the micropore size distribution and formation of larger pores, although the activated carbons remain predominantly microporous. The increase in textural properties after activation is reflected in enhancement of hydrogen storage capacity; activated ZIF-templated carbons prepared at CVD temperature of 700 and 850 °C achieve high hydrogen uptake (at 20 bar and −196 °C) of 6.2 and 5.1 wt%, respectively. Activation also improves the CO2 uptake; the CO2 storage capacity (at 25 °C and 1 bar under flow conditions) increases from ca. 1.8 mmol/g for ZIF-templated carbons to as high as 2.4 mmol/g after activation. The best porosity and gas uptake properties were achieved by a sample whose preparation required temperatures no higher than 700 °C. Our findings show that incorporation of a CVD step not only simplifies the templating process by reducing the temperature required but also removes the need for a washing step prior to activation.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 195, 1 September 2014, Pages 258–265
نویسندگان
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