کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
73241 49052 2013 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Nano-ZSM-5 zeolite: Synthesis and application to electrocatalytic oxidation of ethanol
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Nano-ZSM-5 zeolite: Synthesis and application to electrocatalytic oxidation of ethanol
چکیده انگلیسی


• Synthesis of nanocrystalline zeolite was done under atmospheric condition using clear solution.
• Characterization of synthesized nano zeolite was studied using FT-IR, XRD and SEM techniques.
• Synthesized nano zeolite was used for preparing modified electrode for oxidation of ethanol.
• The rate constant for ethanol oxidation was found to be 1.23 ∗ 106 cm2 s−1 mol−1.

Direct oxidation of small organic alcohols as the fuel for direct alcohol fuel cells leads to large over-voltages with low current on the surface of most unmodified electrodes. Developing new procedures for the electro-catalytic oxidation of ethanol to increase the produced current is very much desirable. This paper reports a new nano-sized zeolite-modified carbon paste electrode (NZMCPE) based on NiZSM-5 for ethanol electro-oxidation. Nano-crystallites of ZSM-5, with an average particle size of around 63 nm, were synthesized using clear solutions at the low temperature of 90 °C under atmospheric pressure. They were characterized using the XRD, FT-IR and SEM techniques. Ni (ІІ) ions were incorporated in the zeolite framework by the immersion of modified carbon paste electrode with the synthesized zeolite in a 0.5 M nickel chloride solution. The electrocatalytic oxidation of ethanol was investigated using the cyclic voltammetry technique and the rate constant for catalytic reaction through chronoamprometric method was calculated 1.23 ∗ 106 cm3 s−1 mol−1.

SEM image of synthesized nano crystalline ZSM-5 zeolite, using a clear solution under atmospheric conditions.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 180, 1 November 2013, Pages 56–60
نویسندگان
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