کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
73276 49053 2014 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Direct synthesis, characterization and catalytic application of SBA-15 mesoporous silica with heteropolyacid incorporated into their framework
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Direct synthesis, characterization and catalytic application of SBA-15 mesoporous silica with heteropolyacid incorporated into their framework
چکیده انگلیسی


• Heteropolyacid incorporated into SBA-15 framework was studied by means of analytic techniques.
• Catalysts were effective for alkylation of o-xylene with styrene.
• Catalysts show superior stability to the HPW/SBA-15-PS catalyst.

The Keggin phosphotungstic acid, H3PW12O40 (HPW) incorporated into SBA-15 ordered mesoporous silica were synthesized via a method involving the introduction of HPW in an acidified solution of P123 triblock copolymer (EO20PO70EO20), the SBA-15 mesostructuring agent (direct synthesis). Samples with similar HPW loadings were also prepared by impregnation of SBA-15. A comparison between direct incorporation of HPW into mesoporous silica and impregnation of HPW on mesoporous silica was done. Characterization by elemental analysis, XRD, N2 adsorption, TEM, DRS-UV and FTIR spectroscopy showed that after calcination HPW in the direct synthesized samples was better dispersed or may even be partially embedded in the pore walls. Moreover, their catalytic behaviors were investigated in the alkylation of o-xylene with styrene. Results show that direct synthesized sample has the better catalytic performances in terms of yield and stability. This behavior may be owing to high dispersion of the HPW species on the SBA-15 and the strong interaction between the HPW and the support, thus prevent HPW leaching from the support.

The Keggin phosphotungstic acid, H3PW12O40 (HPW) incorporated into SBA-15 ordered mesoporous silica were synthesized via a method involving the introduction of HPW in an acidified solution of P123 triblock copolymer (EO20PO70EO20), the SBA-15 mesostructuring agent (direct synthesis). The obtained catalysts were highly effective for alkylation of o-xylene with styrene in terms of yield and stability. Compared with the HPW/SBA-15-PS catalyst (impregnation synthesis method), both the catalytic stability and reusability were greatly enhanced.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 187, 15 March 2014, Pages 7–13
نویسندگان
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