کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
74288 49087 2011 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Fixed-bed removal of Hg2+ from contaminated water by microporous titanosilicate ETS-4: Experimental and theoretical breakthrough curves
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Fixed-bed removal of Hg2+ from contaminated water by microporous titanosilicate ETS-4: Experimental and theoretical breakthrough curves
چکیده انگلیسی

The present study reports the assembly and operation of a fixed bed using the microporous titanosilicate ETS-4 as sorbent. Sorption–desorption cycles were carried out on an ETS-4 fixed-bed, for the removal of Hg2+ from contaminated water. The sorption capacity of the ETS-4 in the column in two consecutive cycles remained constant (33.6 and 33.3 mg g−1, respectively); however due to certain difficulties encountered during ETS-4 packaging and operation mode, breakthrough curves corresponding to these cycles showed dissimilar patterns. A concentration gradient of an EDTA-Na2 solution (0.05–0.25 M) was efficient for bed regeneration, achieving an elution efficiency of 98%. The elution curve had an asymmetrical shape, the concentration peak was attained in less than 5 min, and the concentration factor was 920. Four kinetic models, namely Thomas, Bohart–Adams, Clark and Yoon–Nelson, were applied to predict the breakthrough curves and to estimate the characteristic parameters of the column, which are the basis for the process design at a real scale. The operation of an ETS-4 fixed-bed for the treatment of Hg2+ contaminated waters was shown to be feasible, despite some limitations mainly related with its loose packing.

Figure optionsDownload as PowerPoint slideHighlights
► Assembling and operation of a microporous titanosilicate fixed-bed for Hg removal.
► Theoretical models successfully applied to data from the dynamic fixed-bed study.
► Models predict accurately the breakthrough curves and the column’s parameters.
► High capacity and renewal of the fixed-bed show its viability for multiple cycles.
► Titanosilicate ETS 4 is a safe and effective material to clean Hg polluted water.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 145, Issues 1–3, November 2011, Pages 32–40
نویسندگان
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