کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
74942 | 49104 | 2012 | 5 صفحه PDF | دانلود رایگان |

Mesoporous carbon spheres with a bimodal pore size distribution were prepared by suspension polymerization and steam activation method using phenol–formaldehyde resins as a carbon precursor. The as-prepared carbon spheres had a specific surface area of 1006 m2 g−1, total pore volume of 1.34 cm3 g−1, mesoporous ratio of 81.3% and average pore size of 5.33 nm. Moreover, the carbon material showed a bimodal pore size distribution (3.5 and 23.8 nm). We found a high specific capacitance of 147 F g−1 for the carbon spheres in ionic liquid 1-ethyl-3-methylmidazolium tetrafluoroborate ([EMIm]BF4) at a current density of 2 mA cm−2 and small impedance at the interface of electrode/electrolyte. In addition, a specific energy of 20 Wh kg−1 at a specific power of 3100 W kg−1 was obtained in some particular cases.
Carbons spheres with high specific surface area (1006 m2 g−1) and bimodal pore size distribution (3.5 and 23.8 nm) were successfully prepared by suspension polymerization and steam activation using phenol–formaldehyde resins as a carbon precursor.Figure optionsDownload as PowerPoint slideHighlights
► Suspension polymerization method for preparation of carbon spheres from phenol–formaldehyde resins.
► BET specific surface area of 1006 m2 g−1, mesoporous ratio of 81.3 and average pore size of 5.33 nm.
► Specific capacitance of 147 F g−1 in ionic liquid [EMIm]BF4.
Journal: Microporous and Mesoporous Materials - Volume 151, 15 March 2012, Pages 282–286