کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
75058 49108 2009 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Microwave synthesis of MFI-type zeolite membranes by seeded secondary growth without the use of organic structure directing agents
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Microwave synthesis of MFI-type zeolite membranes by seeded secondary growth without the use of organic structure directing agents
چکیده انگلیسی

This paper reports the microwave synthesis of MFI-type zeolite membranes by secondary growth of nanocrystalline silicalite seed layers in pure inorganic precursors. The inorganic precursor solutions contained SiO2, Al2(SO4)3, NaOH, and H2O. It was found that the membrane formation and quality were sensitive to the Si/Al ratio of the precursor solution. Good quality MFI membranes were obtained from precursors with Si/Al ratios in range 111–130. The membranes had H2/SF6 permselectivity of >1700 and H2 permeance >3 × 10−7 mol m−2 s−1 Pa−1 at 23 °C when helium was used as sweeping gas. The membrane synthesis duration can be greatly shortened by microwave heating as compared to the conventional heating method. Furthermore, membranes obtained from template-free inorganic precursors exhibited higher permselectivties of H2 over N2, and SF6 than the membrane synthesized with TPAOH template. The studies on small gas permeation mechanisms and BET characterization of zeolite particles suggested that the membranes derived from inorganic solutions contained minimized intercrystalline pores by avoiding the high temperature template removal process and possessed slightly smaller effective pore size likely due to trapping of SiO2 molecular species in the zeolite microporosity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 118, Issues 1–3, 1 February 2009, Pages 224–231
نویسندگان
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