کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
75514 | 49117 | 2008 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Thin-layer template-free polycrystalline mordenite membranes on cylindrical mullite supports Thin-layer template-free polycrystalline mordenite membranes on cylindrical mullite supports](/preview/png/75514.png)
Continuous nanoporous mordenite membranes were reproducibly fabricated on tubular microporous mullite supports. The ceramic supports were prepared during calcination of kaolin clay, followed by a leaching post-treatment. A template-free seeded hydrothermal synthesis in a brass autoclave was used to prepare the zeolite membranes. The membranes and the powder crystals collected from the bottom of the autoclave were characterized with XRD, SEM and EDAX. PV properties of the membranes were assessed using dehydration of different ethanol–water mixtures. XRD patterns showed that mordenite was the only zeolitic material present in the membrane. SEM examination of the membrane revealed that thickness of the mordenite crystals filling the voids as a dense thin-layer among the mullite support was 5–10 μm. The continuous top-layer of the membrane was formed by many large and oriented crystals. EDAX analysis showed a Si to Al ratio of 6 for the mordenite powder. The polycrystalline membranes were found to be selective for dehydration of different ethanol/water mixtures. It was concluded that selective adsorption of water on the zeolite pores, small intercrystalline defects and a pinhole-free structure of the membrane layer leaded to high water selectivity of the mordenite membranes studied.
Journal: Microporous and Mesoporous Materials - Volume 114, Issues 1–3, 1 September 2008, Pages 148–154