کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
75577 49118 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Pervaporation through TS-1 membrane
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Pervaporation through TS-1 membrane
چکیده انگلیسی

Titanium-substituted silicalite (TS-1) membranes were synthesized onto the surface of a tubular mullite support by in situ crystallization using tetraethyl orthosilicate (TEOS), titanium tetrabutoxide (TBOT) and tetrapropylammonium hydroxide (TPAOH) as silica, titanium source and organic structure directing agent. The typical molar composition was 1SiO2:0.02TiO2:0.17TPAOH:120H2O. X-ray diffraction (XRD) patterns and Fourier transformed infrared (FT-IR) spectra of zeolite powders and membranes confirmed that the titanium was isomorphously incorporated into the MFI framework. The outer surface of the porous support was completely covered with randomly oriented, intergrown TS-1 crystals and the thickness of the membrane was about 10–20 μm, judging from the scanning electron microscopy observation. The membrane prepared at 200 °C for 16 h showed high ethanol selectivity for an ethanol/water mixture. For example, the separation factor and total flux through this TS-1 membrane were 127 and 0.77 kg/m2 h for 5 wt.% ethanol feed concentration at 60 °C, respectively.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 115, Issues 1–2, 1 October 2008, Pages 164–169
نویسندگان
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