کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7588550 | 1492081 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
On-cartridge derivatisation using a calixarene solid-phase extraction sorbent for facile, sensitive and fast determination of formaldehyde in beer
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کلمات کلیدی
Dichloromethane (PubChem CID: 6344)NCSDCMSPEDNPHACN2,4-dinitrophenylhydrazine - 2،4-dinitrophenylhydrazineBeer - آبجوSolid-phase extraction - استخراج فاز جامدAcetonitrile - استونیتریلAcetonitrile (PubChem CID: 6342) - استونیتریل (PubChem CID: 6342)Phosphoric acid (Pubchem CID: 1004) - اسید فسفریک (Pubchem CID: 1004)Derivatisation - بکارگیریDichloromethane - دیکلورمتانFormaldehyde - فرمالدئیدFormaldehyde (PubChem CID: 712) - فرمالدئید (PubChem CID: 712)Methanol - متانولMethanol (PubChem CID: 887) - متانول (PubChem CID: 887)MeOH - مونhigh performance liquid chromatography - کروماتوگرافی مایع با کارایی بالاHPLC - کروماتوگرافی مایعی کارا
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This work demonstrates the successful application of an on-cartridge derivatisation procedure for facile, fast and sensitive determination of formaldehyde in beer by HPLC-UV. The derivatisation and solid-phase extraction (SPE) were integrated into a novel calixarene SPE sorbent: tetraazacalix[2]arene[2]triazine bonded silica gel. Specifically, 2,4-dinitrophenylhydrazine was adsorbed onto the sorbent in advance, based on the charge-transfer interaction between the macrocyclic molecule and nitrobenzenes. The method was optimised and validated: under the optimal conditions of derivatisation, SPE and HPLC separation, good linearity was obtained in the range of 0.080-3.2 μg mLâ1 with a correlation coefficient of 0.9939, the limit of detection was 3.0 ng mLâ1 (S/N = 3), the limit of quantification was 10 ng mLâ1 (S/N = 10), and the recovery level using this method was desirable at 75-84%. The developed method was successfully applied to determine formaldehyde content in real beer samples; the results were in the range of 0.11-1.1 μg mLâ1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Food Chemistry - Volume 211, 15 November 2016, Pages 314-319
Journal: Food Chemistry - Volume 211, 15 November 2016, Pages 314-319
نویسندگان
Zhifen Deng, Kai Hu, Yongming Zhang, Wenjie Zhao, Fei Wang, Ling Guo, Wenfen Zhang, Juan He, Yanjie Huang, Shusheng Zhang,