کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
75938 49128 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
12-Tungstophosphoric heteropolyacid supported on modified SBA-15 as catalyst in HDS of thiophene
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
12-Tungstophosphoric heteropolyacid supported on modified SBA-15 as catalyst in HDS of thiophene
چکیده انگلیسی

NiW catalysts have been synthesized by loading a Ni salt of the 12-tungstophosphoric heteropolyacid (H3PW12O40) on Al-, Ti- and W- modified SBA-15. The supports and catalysts are characterized by BET, XRD, IR, DRS, TPR and TPD of NH3. Results from XRD and IR measurements confirm the hexagonally ordered mesoporous structure and incorporation of Al, Ti and W into the SBA-15 support. It was found that incorporation of Ti- or W- into the SBA-15 structure increases the reducibility of NiW catalysts. The catalysts are tested in the hydrodesulfurization (HDS) reaction of thiophene. The NiW catalyst supported on W- containing SBA-15 showed higher performance in the HDS of thiophene as compared to the SBA-15 modified with Al and Ti.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 122, Issues 1–3, 1 June 2009, Pages 128–134
نویسندگان
, , , ,