کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7606563 1492949 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Efficient preparation and comprehensive properties of thermal decomposition and detonation for 4,4′-dinitro-3,3′-azofuroxan
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Efficient preparation and comprehensive properties of thermal decomposition and detonation for 4,4′-dinitro-3,3′-azofuroxan
چکیده انگلیسی
The preparation of 4,4′-dinitro-3,3′-azofuroxan (3) was efficiently accomplished from synthesizing the key intermediate of 4-amino-3-azidocarboxyl-furoxan (1) and oxidizing the precursor 4,4′-diamino-3,3′-azofuroxan (2). The structure of 3 and its crystal density of 1.981 g cm−3 were determined by single crystal X-ray diffraction studies. The crystal structure determination indicated that only 3 was obtained rather than its isomers 3,3′-dinitro-4,4′-azofuroxan (3′), which consistent with the results of theoretical calculations. The comprehensive thermal decomposition behaviors were fully characterized by multiple heating methods, TG-DSC-MS and original temperature-dependent/FTIR coupling technique. In addition, the experimental detonation velocity of 3 was determined to be 9778 m s−1 by using a developed method that only requires a small amount of samples on a network plate made of aluminum alloy, which is also well suited for other energetic compounds with high impact sensitivity (IS < 8 J), such as HMX, RDX and CL-20.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Analytical and Applied Pyrolysis - Volume 128, November 2017, Pages 451-458
نویسندگان
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