کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7606905 | 1492968 | 2014 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Py-GC/MS studies and principal component analysis to evaluate the impact of feedstock and temperature on the distribution of products during fast pyrolysis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Py-GC/MS studies and principal component analysis to evaluate the impact of feedstock and temperature on the distribution of products during fast pyrolysis Py-GC/MS studies and principal component analysis to evaluate the impact of feedstock and temperature on the distribution of products during fast pyrolysis](/preview/png/7606905.png)
چکیده انگلیسی
This paper investigates the effect of pyrolysis temperature between 350 and 600 °C on the distribution of pyrolytic products derived from Avicel, α-cellulose, Douglas Fir wood (softwood) and Hybrid Poplar wood (hardwood) by Py-GC/MS as a way to identify the best conditions for bio-oil production. The products were grouped in five families depending on their origin. The C1 family is formed by products of cellulose fragmentation reactions (glycoaldehyde, acetol, 1,2-ethanediol, monoacetate, butanedial). The products grouped in the C2 family (levoglucosan, levoglucosenone, 1,4:3,6-dianhydro-α-d-glucopyranose) are derived from cellulose depolymerization reactions. The molecules derived from hemicellulose (acetic acid, furfural, 2-furanmethanol) were grouped in the H family. The products derived from lignin were grouped in two families L1 (derived from p-hydroxyl phenol (H) and guaiacyl (G) structures) and L2 (derived from syringyl (S) structures). Principal components analysis was used to identify the main factors controlling the distribution of products. Our results show that the yield of most of the pyrolytic products can be explained in the five groups or families described above. Most of the C1 products derived from Avicel, α-cellulose and Douglas Fir fragmentation reactions increase in yield as the temperature increases. In the case of Hybrid Poplar these products reach a maximum at 400 °C. CO2, 2-oxo methyl ester propanoic acid, 1,2-cyclopentanedione, 3-methyl, levoglucosenone, 1,4:3,6-dianhydro-α-d-glucopyranose, 2,5-dimethyl-4-hydroxy-3(2H)-furanone, and most of the phenolic compounds show a response to temperature changes that is independent of the feedstock processed. As the temperature increased the yield of levoglucosenone (product of dehydration reactions) decreased for all the samples studied. Levoglucosan yield is however highly dependent on the feedstock used and, as such, its behavior with temperature changes is more difficult to predict. The maximum yield of the products derived from lignin (L1 and L2) was found between 400 and 450 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Analytical and Applied Pyrolysis - Volume 109, September 2014, Pages 140-151
Journal: Journal of Analytical and Applied Pyrolysis - Volume 109, September 2014, Pages 140-151
نویسندگان
Shi-Shen Liaw, Victor Haber Perez, Shuai Zhou, Oselys Rodriguez-Justo, Manuel Garcia-Perez,