کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7610060 1493477 2016 37 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Rapid fabrication of ionic liquid-functionalized monolithic column via in-situ urea-formaldehyde polycondensation for pressurized capillary electrochromatography
ترجمه فارسی عنوان
ساخت سریع تولید ستون یکپارچه از مایکروویو یونی با استفاده از محلول پلی اکسیده شدن اوره فرمالدئید در محل برای الکترو کروماتوگرافی مویرگی تحت فشار
کلمات کلیدی
یونیک مونولیت ماتریس ساخت سریع، تخمیر اوره فرمالدئید، الکترو کروماتوگرافی مویرگی تحت فشار،
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی
A novel strategy for rapidly fabricating ionic liquid (IL)-bonded multifunctional monolithic stationary phase has been developed by an in-situ polycondensation of urea-formaldehyde (UF) and a lab-made acylamino-functionalized IL (1-acetylamino-propyl-3-methylimidazolium bromide, [AAPMIm]Br). Two polycondensation processes of UF with 1-amino-propyl-3-methylimidazolium bromide or [AAPMIm]Br were evaluated. Several parameters including mass ratio of urea-formaldehyde, amount of [AAPMIm]Br, polycondensation time and reaction temperature were optimized, and the [AAPMIm]Br-bonded monolithic stationary phase could be rapidly synthesized in 10 min with a satisfactory permeability and mechanical stability. Used for pressurized capillary electrochromatography (pCEC), a typical hydrophilic interaction (HI) retention could be obtained in the resultant [AAPMIm]Br-bonded monolith when the content of acetonitrile (ACN) in mobile phase exceeded 20%. Multiple retention mechanisms such as hydrophilic interaction (HI), hydrogen bond (HH), anion-exchange and cation-exclude interactions, were acheived in the [AAPMIm]Br-bonded monolith. Various polar compounds including phenols, benzoic acid and its homologues, and enkephalins have been well separated and thus demonstrated a satisfactory separation performance of the obtained monolith. A facile access is lighted for rapid preparation of ionic liquid-bonded monoliths with multiple retention mechanisms for pCEC.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1449, 3 June 2016, Pages 100-108
نویسندگان
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