کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7681718 | 1495821 | 2013 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Layer-by-layer self-assembly xylenol orange functionalized CdSe/CdS quantum dots as a turn-on fluorescence lead ion sensor
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Layer-by-layer self-assembly xylenol orange functionalized CdSe/CdS quantum dots as a turn-on fluorescence lead ion sensor Layer-by-layer self-assembly xylenol orange functionalized CdSe/CdS quantum dots as a turn-on fluorescence lead ion sensor](/preview/png/7681718.png)
چکیده انگلیسی
A new turn-on fluorescence sensor based on xylenol orange (XO) functionalized CdSe/CdS quantum dots (QDs) is developed for the determination of lead ion. CdSe/CdS QDs were first modified by mercaptoacetic acid (MAA). The MAA-modified QDs were then capped with the natural biopolymer chitosan and the negatively charged XO. The XO-functionalized QDs were formed via the layer-by-layer self-assembly reaction. The fluorescence of the QDs was quenched by electron transfer mechanism after XO was bound to the QDs. Upon the addition of Pb2+, a dramatic enhancement of the fluorescence intensity was observed, which resulted from the coordination between Pb2+ and XO on QDs surface and the disruption of the electron transfer mechanism. Hence the fluorescence of the QDs was recovered. The recovery of the fluorescence intensity showed a good linear relationship with the concentration of Pb2+ added from 0.05 to 6 μmol Lâ1. A detection limit of 0.02 μmol Lâ1 was achieved. This method was successfully applied to the determination of lead in real samples with satisfactory results.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Talanta - Volume 114, 30 September 2013, Pages 110-116
Journal: Talanta - Volume 114, 30 September 2013, Pages 110-116
نویسندگان
Qin Zhao, Xiaolong Rong, Li Chen, Hongbing Ma, Guanhong Tao,