کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7681736 | 1495820 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Sensitive determination of paraquat by square wave anodic stripping voltammetry with chitin modified carbon paste electrode
ترجمه فارسی عنوان
تعیین حساسیت پاراکات توسط ولتامتری سدی آنودی مربع و با الکترودهای کربن اصلاح شده کیتین
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی
A novel analytical approach has been developed and evaluated for the quantitative analysis of paraquat herbicides which can be found at trace levels in olive oil and olives. The aim of this work is to optimize all factors that can influence this determination by a carbon paste electrode modified with chitin (Chit-CPE). The best responses were obtained with square wave potential in diluted Na2SO4 as supporting electrolyte. The influence of various parameters on the Chit-CPE was investigated. Under the optimized working conditions, calibration graphs were linear in the concentration ranges of 5.0Ã10â9-1.0Ã0â5 mol Lâ1. For 180 s preconcentration, detection limits of 2.67Ã10â10 mol Lâ1 (peak 2) was obtained at the signal noise ratio (SNR) of 3. To evaluate the reproducibility of the newly developed electrode, the measurements of 1.0Ã10â5 mol Lâ1 PQ were carried out for seven times at Chit-CPE and the relative standard deviation was 5.2%. The analytical methodology was successfully applied to monitor the paraquat content in olives and olive oil.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Talanta - Volume 115, 15 October 2013, Pages 172-177
Journal: Talanta - Volume 115, 15 October 2013, Pages 172-177
نویسندگان
H. El Harmoudi, M. Achak, A. Farahi, S. Lahrich, L. El Gaini, M. Abdennouri, A. Bouzidi, M. Bakasse, M.A. El Mhammedi,