کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7690556 | 1495961 | 2018 | 19 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Vibrational properties of L-cysteine hydrochloride monohydrate crystal under high-pressure
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Vibrational properties of L-cysteine hydrochloride monohydrate crystal under high-pressure Vibrational properties of L-cysteine hydrochloride monohydrate crystal under high-pressure](/preview/png/7690556.png)
چکیده انگلیسی
L-cysteine hydrochloride monohydrate crystals, C3H7NO2S·HCl·H2O, were studied by Raman spectroscopy as a function of pressure in a diamond anvil cell up to 6.2âGPa in the spectral range 3500â30 cmâ1. From the analysis of the results, we inferred that the crystal is structurally stable in this pressure range. Some changes on the Raman spectra were observed for bands related to vibrational modes of the SH, NH3+, CH2, CCN, OH and COH units. These modifications were associated with conformational changes of the molecules in the unit cell undergone at high pressures. Comparing this behavior with those of L-cysteine, DL-cysteine and L-cysteine hydrochloride crystals in the same pressure range, we note greater stability for the hydrochloride monohydrate form. In the L-cysteine hydrochloride monohydrate crystal, the chloride ion and water molecule play an essential role in increasing the number of the hydrogen bonds, improving the structural stability of the crystal.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 98, September 2018, Pages 92-97
Journal: Vibrational Spectroscopy - Volume 98, September 2018, Pages 92-97
نویسندگان
J.F. Silva Junior, G.D.S. Souza, C.L. Lima, P.T.C. Freire, G.S. Pinheiro,