کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7691161 | 1495975 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermal and plasma synthesis of metal oxide nanoparticles from MOFs with SERS characterization
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Aluminum oxide (Al2O3) and chromium oxide (Cr2O3) nanoparticles were synthesized by thermolysis of metal-organic frameworks (MOFs). Further O2 plasma treatment is required to obtain high crystalline quality metal oxides. The composition and morphology of metal oxide nanoparticles were confirmed by powder X-ray diffraction and scanning electron microscopy characterization, respectively. The quality of synthesized metal oxides was also examined by observing the surface-enhanced Raman scattering (SERS) spectra of methyl orange adsorbed on Al2O3 and Cr2O3. The observed SERS effect can be ascribed to charge-transfer (CT) resonance effect between methyl orange and metal oxide surfaces. UV-vis absorption spectra and DFT calculations of metal oxide- methyl orange complexes have confirmed that the observed SRS effect is due to CT resonance between the metal oxide nanoparticles and the adsorbed methyl orange molecules.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 84, May 2016, Pages 146-152
Journal: Vibrational Spectroscopy - Volume 84, May 2016, Pages 146-152
نویسندگان
Bing-Han Li, Tsung-Han Yu, Cheng-Yu Weng, Chung-Chun Yang, Chia-Her Lin, Szetsen Lee,