کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7691248 | 1495986 | 2014 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
In-plane chemical pressure in (U1âyCey)O2 studied by Raman spectroscopy
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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![عکس صفحه اول مقاله: In-plane chemical pressure in (U1âyCey)O2 studied by Raman spectroscopy In-plane chemical pressure in (U1âyCey)O2 studied by Raman spectroscopy](/preview/png/7691248.png)
چکیده انگلیسی
We investigate the nature of bonding and charge states in (U1âyCey)O2 (y = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) by Raman spectroscopy. Raman spectrum of UO2 exhibits two prominent bands below 1000 cmâ1, a F2g mode at 446 cmâ1 and a F1u LO mode at 578 cmâ1. As y is increased from 0 to 0.6, the F1u exhibits a large blue shift of 90 cmâ1, and from y = 0.6 to 1.0, a red shift of 54 cmâ1. We show that our results can be interpreted as arising from anisotropic compression/relaxation of the lattice under Ce substitution and this can give an indication of its charge states. Alternate interpretations have been given in the literature on the effect of substituents and dopants to the Raman spectra of UO2 and CeO2. The present interpretation of chemical stress effects can be taken as another plausible explanation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 73, July 2014, Pages 97-101
Journal: Vibrational Spectroscopy - Volume 73, July 2014, Pages 97-101
نویسندگان
T.R. Ravindran, R. Venkata Krishnan,