کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
76978 | 49153 | 2006 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mesoporous MSU materials functionalized with sulfonic group: A multinuclear NMR and theoretical calculation study
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The structure and acidity of sulfonic group functionalized mesoporous materials with MSU structure were characterized in detail using multinuclear NMR technique in combination with other approaches such as XRD, N2 adsorption and desorption, as well as density function theory (DFT) calculation. Our experimental and theoretical calculation results indicate that functionalized MSU–SO3H materials with well-ordered mesostructure have been successfully synthesized and the materials have acid strength slightly weaker than that of microporous zeolite HZSM-5, which may be helpful for the understanding of some acid-catalyzed reactions, such as alkylation and esterification, occurring on sulfonic-functionalized mesoporous materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 89, Issues 1–3, 24 February 2006, Pages 219–226
Journal: Microporous and Mesoporous Materials - Volume 89, Issues 1–3, 24 February 2006, Pages 219–226
نویسندگان
Jiqing Wang, Ningya Yu, Anmin Zheng, Jun Yang, Dong Wu, Yuhan Sun, Chaohui Ye, Feng Deng,