کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7706896 | 1497312 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Vibrational and thermodynamic properties of LiBH4 polymorphs from first-principles calculations
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Vibrational and thermodynamic properties of LiBH4 polymorphs from first-principles calculations Vibrational and thermodynamic properties of LiBH4 polymorphs from first-principles calculations](/preview/png/7706896.png)
چکیده انگلیسی
The study of phonons describes the thermodynamic properties behavior of compounds with small atoms because phonons have an important influence on its properties. Lithium borohydride, LiBH4, is one of the suitable materials for hydrogen storage solid state. Although the transformations of Lithium borohydride LiBH4 were repeatedly studied by experiments and fundamental side, these transformations are still under discussion. In the present work, the mode vibrational analysis of orthorhombic and hexagonal LiBH4 structures were considered with ab initio lattice-dynamics based on the quasi-harmonic approximation approach as implemented in Phonopy code. The results show that the orthorhombic structure is thermodynamically stable, while the hexagonal structure is unstable owing to the presence of negative mode frequency. The thermal expansion behavior and various thermodynamic properties stability like heat capacity, entropy and Helmholtz energy were also studied and the obtained results are in good agreement with experiments. This shows a deep connection between stability and strength and helps researchers to estimate accurately the thermodynamic performance of LiBH4 materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 43, Issue 13, 29 March 2018, Pages 6625-6631
Journal: International Journal of Hydrogen Energy - Volume 43, Issue 13, 29 March 2018, Pages 6625-6631
نویسندگان
H. Benzidi, M. Garara, M. Lakhal, M. Abdalaoui, A. Benyoussef, A. El kenz, M. Louilidi, M. Hamedoun, O. Mounkachi,