کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7712917 | 1497424 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrogen occlusion behaviors of ZrVFe alloys under mild hydrogen pressures and lowering of their hydrogen desorption temperatures
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Four kinds of ZrVFe alloys with the C14 Laves phase structure had high hydrogen storage capacity under mild pressures, and those alloys would be promising for widespread application such as recovery of hydrogen derived from water splitting. Addition of titanium to ZrVFe lowered hydrogen desorption temperatures through increase of equilibrium pressures. Substitution of ferrovanadium for vanadium did not deteriorate hydrogen occlusion performance of ZrVFe, and provided with lower cost alloys. Another way to reduce the cost would be elimination of purifying step of vanadium prepared by the thermite process, but remaining aluminum proved to bring about lower hydrogen capacity, as evidenced by comparative experiments including a ZrVFe alloy with aluminum intendedly added. Every alloy had fairly good cycling durability except the one contaminated with aluminum.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 1, 5 January 2016, Pages 425-430
Journal: International Journal of Hydrogen Energy - Volume 41, Issue 1, 5 January 2016, Pages 425-430
نویسندگان
Yasuhiro Watanuki, Takeshi Toyama, Yoshiyuki Kojima, Nobuyuki Nishimiya,