کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7715698 | 1497458 | 2015 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, characterization and electrocatalytic activity of Co@Pt nanoparticles supported on carbon-ceramic substrate for fuel cell applications
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this study, we report the synthesis of Co@Pt nanoparticles via a fast and simple method and the fabrication of an anodic electrocatalyst, Co@Pt supported on carbon-ceramic substrate, for fuel cell applications. The present synthesis method is very facile and economical which may be suitable for large-scale production of Co@Pt nanoparticles with high activity. The surface morphology, structure and composition of the as-prepared core-shell nanoparticles were characterized by scanning electron microscopy, high resolution transmission electron microscopy, X-ray diffraction, and energy dispersive X-ray spectroscopy. Then, the electrooxidation of ethylene glycol (EG) and glycerol (Gly) was investigated on the Co@Pt nanoparticles supported on carbon-ceramic electrode (Co@Pt/CCE) in 0.5Â M H2SO4 solution. Electrocatalytic characteristics were methodically investigated by electrochemical techniques such as cyclic voltammetry and chronoamperometry. The Co@Pt/CCE electrocatalyst demonstrates improved specific activity toward EG and Gly electrooxidation compared to the Pt-alone nanoparticles supported on carbon-ceramic electrode (Pt/CCE) and also shows much high structural stability and tolerance to carbonaceous species poisoning. Therefore, the Co@Pt/CCE can be extended as a promising electrocatalyst for the polyol alcohols electrooxidation reactions in fuel cells.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 15, 27 April 2015, Pages 5115-5125
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 15, 27 April 2015, Pages 5115-5125
نویسندگان
Biuck Habibi, Serveh Ghaderi,