کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7717997 | 1497474 | 2014 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
NiOx nanoparticles supported on polyethylenimine functionalized CNTs as efficient electrocatalysts for supercapacitor and oxygen evolution reaction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: NiOx nanoparticles supported on polyethylenimine functionalized CNTs as efficient electrocatalysts for supercapacitor and oxygen evolution reaction NiOx nanoparticles supported on polyethylenimine functionalized CNTs as efficient electrocatalysts for supercapacitor and oxygen evolution reaction](/preview/png/7717997.png)
چکیده انگلیسی
Ni oxide based nanoparticles (NPs) have been widely used as electrocatalysts in the electrochemical energy storage and conversion applications. In this paper, NiOx NPs are successfully synthesized by the self-assembly of Ni precursor onto polyethylenimine functionalized carbon nanotubes (PEI-CNTs) assisted with microwave radiation. NiOx NPs with size around 2-3Â nm are homogenously dispersed on the PEI-CNTs supports with no aggregation. The electrochemical activity of NiOx NPs on PEI-CNTs, NiOx/PEI-CNTs, as effective electrocatalysts is studied for supercapacitor and oxygen evolution reaction in alkaline solutions. NiOx/PEI-CNTs show a capacitance of 1728 and 1576Â FÂ gâ1 based on active material, and 221 and 394Â FÂ gâ1 based on total catalyst loading on 12.5% and 25% NiOx/PEI-CNTs, respectively, which is substantially higher than 152Â FÂ gâ1 of unsupported NiO. The NiOx/PEI-CNTs electrodes exhibit reversible and stale capacitance of â¼1200Â FÂ gâ1 based on active materials after 2000Â cycles at a high current density of 10Â AÂ gâ1. NiOx/PEI-CNTs also exhibit significantly higher activities for oxygen evolution reaction (OER) of water electrolysis, achieving a current density of 100Â AÂ gâ1 at an overpotential of 0.35Â V for 25% NiOx/PEI-CNTs. It is believed that the uniformly dispersed nano-sized NiOx NPs and synergistic effect between the NiOx NPs and PEI-CNTs is attributed to the high electrocatalytic performance of NiOx/PEI-CNTs electrocatalysts. The results demonstrate that NiOx NPs supported on PEI-CNTs are highly effective electrocatalysts for electrochemical energy storage and conversion applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 35, 3 December 2014, Pages 20662-20670
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 35, 3 December 2014, Pages 20662-20670
نویسندگان
Yi Cheng, Pei Kang Shen, San Ping Jiang,