کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
7718074 1497482 2014 9 صفحه PDF سفارش دهید دانلود رایگان
عنوان انگلیسی مقاله ISI
Interaction mechanism of hydrogen storage materials with layer-by-layer applied protective polyelectrolyte coatings
ترجمه فارسی عنوان
مکانیزم تعامل مواد ذخیره سازی هیدروژن با لایه های لایه پوشش محافظ پلی الکترولیتی
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کلمات کلیدی
مواد ذخیره سازی هیدروژن، هیدرید فلزی، پلی الکترولیت ها، لایه های پوشش محافظتی، بورو هیدرید سدیم،
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
چکیده انگلیسی
Metal hydrides are promising compounds for the storage of hydrogen especially in the transport sector. Their high reactivity with moisture and difficult handling in ambient atmosphere prevents their easy application in tanks and thus the market penetration of this very promising and clean technology. In the present work we investigated the way to protect sodium borohydride with organic polyelectrolytes like polyethyleneimine (PEI) and dicarboxy terminated poly(acrylonitrile-co-butadiene-co-acrylic acid) (PABA) with emphasis on the interaction of those polyelectrolytes with the SBH. The polyelectrolytes protect SBH either by electrostatic adsorption or by reacting with it, depending on the reactive groups present in their structure. PABA undergoes only an electrostatic interaction with the SBH substrate. PEI on the other hand interacts chemically with the SBH substrate and forms complexes with groups on the SBH surface. Both polyelectrolytes can be applied in a layer-by-layer approach on the SBH in order to protect it. Regarding the best order of the layer application XPS results yield that the formation of the boron-amino-complexes between the PEI and the SBH is independent of the order in which the PABA and PEI layers are applied. However, the rearrangement of the SBH surface groups due to the application of the PEI films has been found to be considerably influenced by the order of application. The effect of a PEI film has been mostly compensated by the subsequent application of a PABA film, while the application of PEI had a much larger influence on the surface of a PABA coated SBH sample. Thus, the best order of the layer application with respect to the application according to XPS is to deposit the PEI layer at first and the PABA layer afterwards.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 27, 12 September 2014, Pages 14834-14842
نویسندگان
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