کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7721489 | 1497516 | 2013 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Investigation of AuNi/C anode catalyst for direct methanol fuel cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
AuNi nanoparticles supported on the activated carbon (AuNi/C) are synthesized by the impregnation method in the ethyleneglycol system using NH2NH2·H2O as a reducing agent. The alloying of Au and Ni and the removal of unalloyed Ni in the AuNi/C composition are achieved by heat and acid treatments in sequence. Research results reveal that the average size and alloying degree of the AuNi nanoparticles in the AuNi/C catalyst increase with the enhancement of the annealing temperature. However, the Ni content of the AuNi/C catalyst firstly goes up and then down with the rising of heat treatment temperature due to the AuNi system phase-separates. Moreover, the electrocatalytic activity normalized by the electrochemically active surface area of each AuNi/C catalyst is far better than that of the Au/C catalyst, because of the bifunctional mechanism and the electrocatalytic activity of the NiOOH. In particular, the AuNi/C catalyst annealed at 400 °C exhibits the most excellent activity, due to its small AuNi particles and proper alloying degree. Furthermore, its mass-specific electrochemical activity is higher than that of the Au/C catalyst, although the mean diameter of the AuNi nanoparticles in this catalyst is larger than that of the Au nanoparticles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 29, 30 September 2013, Pages 12838-12846
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 29, 30 September 2013, Pages 12838-12846
نویسندگان
Shaohui Yan, Lizhen Gao, Shichao Zhang, LiLi Gao, Weike Zhang, Yuzhen Li,