کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7722499 | 1497523 | 2013 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effects of charge balance with Na+ on SrTiO3:Mo6+ prepared by spray pyrolysis for H2 evolution under visible light irradiation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Photocatalyst powders of SrTi1âxMoxO3 and Sr1â2xNa2xTi1âxMoxO3 were prepared by spray pyrolysis for hydrogen evolution for the first time from aqueous methanol solution under visible light irradiation. The co-doping of Mo6+/Na+ ions resulted in increase of BET surface area and pore volume, and formation of unique morphology with wrinkled, furrowed and porous surface, without significant distortion of lattice structure of host material. The hydrogen evolution rate of Sr1â2xNa2xTi1âxMoxO3 photocatalyst was enhanced up to 1115.8 μmol gâ1 hâ1 with an induction period of 1 h under visible light irradiation, which was 1.5 times higher than that of SrTi1âxMoxO3. The co-dopant Na+ ion contributed to the charge balance in the host material by compromising the excess positive charge of Mo6+, which was effective for enhancing the hydrogen evolution rate. The optimum composition of photocatalyst corresponding to the maximum hydrogen evolution rate was Sr1â2xNa2xTi1âxMoxO3 (x = 0.004).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 22, 26 July 2013, Pages 9198-9205
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 22, 26 July 2013, Pages 9198-9205
نویسندگان
Hyun Woo Kang, Seung Bin Park, Ah-Hyung Alissa Park,