کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7724413 | 1497590 | 2011 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The influence of Cu substitution on the hydrogen sorption properties of magnesium rich Mg-Ni films
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The influence of Cu substitution on the hydrogen sorption properties of magnesium rich Mg-Ni films The influence of Cu substitution on the hydrogen sorption properties of magnesium rich Mg-Ni films](/preview/png/7724413.png)
چکیده انگلیسی
This paper describes the hydrogen storage properties of Magnesium rich ternary Mg-Ni-Cu films of 1.5 μm thickness using binary Mg-Ni and Mg-Cu as baselines, and aims to elucidate the precise influences of alloying element Cu on the hydrogen sorption kinetics, thermodynamics and cycleability. Mg-rich Mg-Ni-(Cu) alloys show two stages during absorption. The first stage due to the absorption of Mg not alloyed in the form of Mg2Ni and Mg2Cu, hereafter denoted as free-Mg, is very quick, but the second one due to the absorption of intermetallic Mg2Ni and/or Mg2Cu is significantly slower. This sequence is confirmed by XRD characterizations at different absorption stages. The rapid first stage absorption is mainly catalyzed by the intermetallic phase, Mg2Ni. Cu substitution improves the desorption kinetics, but severely decreases the kinetics of the second absorption stage. Failure to completely absorb Mg2Cu to MgH2 and MgCu2 in consecutive absorption cycles leads to complete loss of desorption-ability in binary Mg-15 at.%Cu. XRD combined with TEM shows that segregation of Mg2Cu towards the grain boundaries is responsible for this. Pressure-Composition Isotherms are used to examine the thermodynamic properties of the alloys. The thermodynamic properties of the Low-Temperature (LT-) Mg2NiH4 are determined for the first time experimentally, and are found to be ÎH = â78.6 kJ/mol H2 and ÎS = â147.83 J/K-mol H2. It is found that the Cu substitution has no influence on the plateau pressure of MgH2 from free-Mg phase, but slightly increases the plateau pressure of LT-Mg2NiH4.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 36, Issue 3, February 2011, Pages 2154-2164
Journal: International Journal of Hydrogen Energy - Volume 36, Issue 3, February 2011, Pages 2154-2164
نویسندگان
X. Tan, M. Danaie, W.P. Kalisvaart, D. Mitlin,