کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7732557 | 1497945 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
In-situ synthesis of vanadium pentoxide nanofibre/exfoliated graphene nanohybrid and its supercapacitor applications
ترجمه فارسی عنوان
سنتز موضعی نانویایبرید گرافن نانوفیبری پنتوکسی وانادیوم و سوپراسپتور آن
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کلمات کلیدی
نانوییدرید، نانوفیبری پنتوکسی وانادیوم، گرافن خرد شده مرفولوژی، خازن های الکتروشیمیایی، ابر مخزن نامتقارن،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
چکیده انگلیسی
A novel nanohybrid material composed of vanadium pentoxide nanofibres (VNFs) and exfoliated graphene were prepared by in-situ growth of VNFs onto graphene nanosheets, and explicated as electrode material for supercapacitor applications. The existence of non-covalent interactions between VNFs and graphene surfaces was confirmed by Raman and Fourier transform infrared (FTIR) spectroscopes. Morphological analysis of the nanohybrid revealed that the VNF layer uniformly grown on the graphene surfaces, producing high specific surface area and good electronic or ionic conducing path. High crystalline structure with small d-spacing of the VNFs on graphene was observed in X-ray diffraction (XRD) analysis. Compared to pristine VNF, the VNF/graphene nanohybrid exhibited higher specific capacitance of 218 F gâ1 at current density of 1 A gâ1, higher energy density of 22 Wh kgâ1 and power density of 3594 W kgâ1. Asymmetric supercapacitor devices were prepared using the Spectracarb 2225 activated carbon cloth and VNF/graphene nanohybrid as positive and negative electrode, respectively. The asymmetric device exhibited capacitance of 279 F gâ1 at 1 A gâ1, energy density of 37.2 Wh kgâ1 and power density of 3743 W kgâ1, which are comparable and or superior to reported asymmetric devices consisting of carbon material and metal oxide as electrode components.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 287, 1 August 2015, Pages 283-290
Journal: Journal of Power Sources - Volume 287, 1 August 2015, Pages 283-290
نویسندگان
Arup Choudhury, Jeliza S. Bonso, Melissa Wunch, Kap Seung Yang, John P. Ferraris, Duck J. Yang,