کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7747976 1498722 2015 68 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Enantioselective dialkylzinc-mediated alkynylation, arylation and alkenylation of carbonyl groups
ترجمه فارسی عنوان
آلکینیل کردن، آریلیت و آلکینیل کردن گروه های کربونیل
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی
Enantiopure diarylmethanols, propargylic and allylic alcohols are important building blocks for the synthesis of a plethora of natural products and pharmaceutically relevant compounds. Among several methods employed for their synthesis, the enantioselective addition of diorganozinc compounds to carbonyl compounds in the presence of appropriate ligands becomes increasingly significant. In this comprehensive review, methods based on the use of readily available diethyl- and dimethylzinc for the formation of more complex compounds are compared and discussed. Available data on the mechanisms and transition states of reactions are presented.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Coordination Chemistry Reviews - Volume 299, 1 September 2015, Pages 83-150
نویسندگان
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