A new vanadium(IV)-bridged polyoxotungstate containing mixed valence-antimony(III,V)

A new mixed-valence SbV/III containing vanadium-substituted polyoxotungstate Na10[{SbV(OH)3}2{VIVO(H2O)}2{SbIIIW9O33}2]·32H2O (1-Na) has been synthesized and structurally characterized.