Ni(II)/Zn(II)-triazolate clusters based MOFs constructed from a V-shaped dicarboxylate ligand: Magnetic properties and phosphate sensing

Two isomorphous MOFs based on four kinds of SBUs were obtained under the same reaction condition. Both of complexes present a three dimensional 8-c framework with whc1 topology. Moreover, complex 1 shows antiferromagnetic behaviour, and 2 could be used as a fluorescence sensor for sensing PO43- anion in aqueous solutions.228