کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7759568 1500106 2014 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Gas adsorption/separation properties of metal directed self-assembly of two coordination polymers with 5-nitroisophthalate
ترجمه فارسی عنوان
خصوصیات جذب / جداسازی گازهای فلزی از دو پلیمر همگام با 5 نیتروس ایزوفلات
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
چکیده انگلیسی
In this study, two new coordination polymers, namely, [Co(µ-nip)(µ-bpe)]n (1) and [Zn(µ-nip)(µ-bpe)]n (2) (nip: 5-nitroisophthalate, bpe: 1,2-bis(4-pyridyl)ethane) were hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, IR spectroscopy, elemental analysis and thermal analysis. Moreover, atomically detailed simulation studies of complex 2 for CO2/CH4 adsorption and separation were performed. Complex 1 consists of two dimensional (2D) (4,4) grid networks with the point symbol of 44.62. Complex 2 exhibits a 3-fold interpenetrating 3D framework with 65.8-dmp topology. Simulation studies demonstrated that complex 2 can separate CO2 from CH4 at low pressures at 273 K.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Solid State Chemistry - Volume 210, Issue 1, February 2014, Pages 280-286
نویسندگان
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