کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7791084 | 1500645 | 2014 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Antisolvent precipitation of water-soluble hemicelluloses from TMP process water
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کلمات کلیدی
Mannose (PubChem CID: 18950)Arabinose (PubChem CID: 66308)Process water - آب تصفیه شدهEthanol (PubChem CID: 702) - اتانول (PubChem CID: 702)Acetone (PubChem CID: 180) - استون (PubChem CID: 180)Antisolvent precipitation - بارش ضد حریقThermomechanical pulping - خمیر ترمومکانیکیRecovery - ریکاوریFlotation - شناورMethanol (PubChem CID: 887) - متانول (PubChem CID: 887)Hemicelluloses - همودیالیزGalactose (PubChem CID: 6036) - گالاکتوز (PubChem CID: 6036)Glucose (PubChem CID: 79025) - گلوکز (PubChem CID: 79025)
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
During the thermomechanical pulping (TMP) of spruce, hemicelluloses (mainly galactoglucomannans, GGMs) are released into the process water at relatively low concentrations that are currently impossible to efficiently recover. This paper examines the recovery of hemicelluloses precipitated from TMP process water via solubility reduction by adding antisolvents such as methanol, ethanol, and acetone. The phase separation was monitored by turbidity measurements. Gravimetric analysis, FTIR, GC-MS, UV spectroscopy, and ICP-OES were used to determine the yield, purity, and composition of the precipitates. Gel permeation chromatography and pulsed field-gradient self-diffusion NMR were used to measure the molecular mass distribution of the precipitates. Acetone was found to be the most efficient antisolvent, giving the highest yield at the lowest addition. The contents of lipophilic extractives and lignin impurities were below 0.5% and 1.6%, respectively, and the metal content was approximately 2% in the precipitates obtained with acetone.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 113, 26 November 2014, Pages 411-419
Journal: Carbohydrate Polymers - Volume 113, 26 November 2014, Pages 411-419
نویسندگان
Dariusz Zasadowski, Jiayi Yang, HÃ¥kan Edlund, Magnus Norgren,