کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
77991 49312 2014 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Large active area inverted tandem polymer solar cell with high performance via alcohol treatment on the surface of bottom active layer P3HT:ICBA
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Large active area inverted tandem polymer solar cell with high performance via alcohol treatment on the surface of bottom active layer P3HT:ICBA
چکیده انگلیسی


• High quality PEDOT:PSS film can form on P3HT:ICBA surface after alcohol treatment.
• P3HT:ICBA surface with alcohol treatment can increase the efficiency of inverted PSC.
• The PEDOT:PSS/ZnO NP is a promising interlayer in large area inverted t-PSC.
• A PCE of 7.00% can be obtained in a 1 cm2 inverted tandem PSC.

We propose that treating the surface of the bottom subcell active layer composed of regioregular poly(3-hexylthiophene) (P3HT): indene-C60-bisadduct (ICBA) with 1-hexanol can improve the wettability of aqueous PEDOT:PSS on its top as a hole transport layer in the inverted tandem polymer solar cell (t-PSC), allowing a fabrication of large area device with power conversion efficiency (PCE) close to small area device. The device structure of the inverted t-PSC is ITO/ZnO(sol–gel)(30 nm)/P3HT:ICBA(1:1, w/w) (180 nm)/treatment with alcohol/PEDOT:PSS(80 nm)/ZnO nanoparticles (ZnO NP)(25 nm)/Poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl}) (PTB7): PC71BM (1:1.5, w/w)(90 nm) /MoO3(15 nm)/Ag(100 nm). For the small-area (0.02–0.03 cm2) device, its PCE can be enhanced form 7.06% to 8.10% by treating with 1-hexanol on P3HT:ICBA surface, resulting from more efficient hole collection for the bottom subcell by the improved film formation of PEDOT:PSS. As the device area is enlarged to 1 cm2, the PCE can be enhanced from 2.19% to 7.00% by the same alcohol treatment.

Film uniformity of aqueous PEDOT:PSS on the surface of hydrophobic P3HT:ICBA can be improved by surface treatment with alcohol of appropriate alkyl chain length, which results in an improvement in PCE of inverted t-PSC therewith, especially for large area device. The PCE with 1-hexanol treatment can reach 7.00% for the inverted t-PSC having large active area (about 1 cm2).Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solar Energy Materials and Solar Cells - Volume 128, September 2014, Pages 240–247
نویسندگان
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