کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7804549 | 1501354 | 2016 | 21 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and characterization of novel indacenodithiophene-based narrow band-gap polymers with pendant isoindigo units for polymer solar cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Two novel indacenodithiophene (IDT) based donor-acceptor (D-A) narrow band-gap polymers PIDTBDTID and PIDTBDT(ID)2 were designed and synthesized, where one/two isoindigo (ID) moieties were introduced into the backbone as the acceptor unit. The PIDTBDTID containing one ID unit exhibited better light-harvesting properties and charge transport properties. On the other hand, the PIDTBDT(ID)2 with two ID units displayed lower the highest occupied molecular orbital energy levels (HOMO). Using these polymers as electron donors and PC71BM as electron acceptor, polymer solar cells based on PIDTBDTID exhibited better photovoltaic performance with a power conversion efficiency (PCE) of 2.66%, an open-circuit voltage (VOC) of 0.87Â V and an enhanced short-circuit current (JSC) of 7.24Â mAÂ cmâ2. While the PIDTBDT(ID)2-based PSCs shown a PCE of 2.50%, an improved VOC of 0.93 V and an JSC of 6.34Â mAÂ cmâ2.121
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: European Polymer Journal - Volume 81, August 2016, Pages 307-315
Journal: European Polymer Journal - Volume 81, August 2016, Pages 307-315
نویسندگان
Wenhong Peng, Hua Tan, Manjun Xiao, Jianhua Chen, Qiang Tao, Xiongwei Duan, Yafei Wang, Yu Liu, Renqiang Yang, Weiguo Zhu,