Crystal structures and the enthalpy changes of liquid-phase reaction of two energetic zinc (II) complexes based on 5,5′-azoterazolate and two chelated co-ligands

Two Zn(II) complexes 1 and 2 based on 5,5′-azotetrazolate are described, which exhibit structural diversity due to the difference of co-ligands. The enthalpy changes of liquid-phase reaction were determined by microcalorimetry.308