کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7809297 1501696 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Tris(acetonitrile)chloropalladium tetrafluoroborate synthesis, application and structural analysis
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Tris(acetonitrile)chloropalladium tetrafluoroborate synthesis, application and structural analysis
چکیده انگلیسی
Results of the single crystal X-ray diffraction analysis of tris(acetonitrile)chloropalladium tetrafluoroborate [PdCl(CH3CN)3]BF4 are presented in details. It was found that the title compound crystallises in the monoclinic system, in the space group C2/c. The role of charge-assisted C-H⋅⋅⋅F-B interactions in crystal architecture was investigated. Due to its untypical properties the prepared [PdCl(CH3CN)3]BF4 has proved to be an excellent palladium source in the synthesis of phosphine-palladium complexes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1121, 5 October 2016, Pages 135-141
نویسندگان
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