کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7810712 | 1501766 | 2013 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Characterization of phase transitions of [N(CH3)4]2ZnCl2Br2 mixed crystals
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Characterization of phase transitions of [N(CH3)4]2ZnCl2Br2 mixed crystals Characterization of phase transitions of [N(CH3)4]2ZnCl2Br2 mixed crystals](/preview/png/7810712.png)
چکیده انگلیسی
The X-ray powder diffraction patterns show that at room temperature [N(CH3)4]2ZnCl2Br2 crystallizes in the orthorhombic system with Pnma space group. Three endothermic peaks at T1 = 251 K, T2 = 276 K and T3 = 283 K are observed by differential scanning calorimetry technique. In order to characterize these transitions, Raman spectra have been recorded in the wide temperature range (between 170 and 400 K) and the frequency range related to the internal and external vibrations of the cations and anions (3200-20 cmâ1). The evolution of Raman spectra against temperature shows that the compound is homogeneous, and singularities occur in the vicinity of 283 K and especially at 251 K. The second goal of the present work was to obtain the Tc temperature transition using the dielectric measurements at different temperatures. Measurements of the dielectric constant εâ², εⳠand tan δ at several temperatures showed that this compound becomes ferroelectric below 257 K. The impedance spectra and the complex modulus show double relaxation peaks in the paraelectric phase, which suggests the presence of grains and grain boundaries in this sample.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 1048, 24 September 2013, Pages 287-294
Journal: Journal of Molecular Structure - Volume 1048, 24 September 2013, Pages 287-294
نویسندگان
K. Karoui, A. Ben Rhaiem, F. Jomni, J.L. Moneger, A. Bulou, K. Guidara,