کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
78169 49319 2014 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Computational comparison of conventional and inverted organic photovoltaic performance parameters with varying metal electrode surface workfunction
ترجمه فارسی عنوان
مقایسه محاسباتی پارامترهای عملکرد فیزیکی آلی معمولی و معکوس با کارکرد سطوح مختلف الکترودهای فلزی
کلمات کلیدی
دستگاه معکوس، روشهای محاسباتی، کارکرد الکترودهای فلزی، فتوولتائیک فیزیکی هیدروژن فیزیکی، پارامترهای عملکرد
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی


• Performance parameters were calculated for OPVs for a range of metal electrodes.
• High workfunction metal electrodes resulted in high-efficiency inverted OPVs.
• Presence of native metal oxides was shown to be detrimental to conventional OPVs.
• Presence of native metal oxides led to high-efficiency inverted OPVs.
• Formation of an interface dipole was shown to improve OPV efficiency

Inverted polymer-based bulk-heterojunction organic photovoltaic (BHJ-OPV) device designs have enabled a breakthrough in operational lifetime through use of stable electrode materials. To date, there have not been systematic performance parameter comparisons between conventional and inverted devices that consider a range of different metal electrodes and presence of native metal oxides at the organic-metal interface. Here, we systematically compute optical and electronic performance parameters for both conventional and inverted BHJ-OPV devices for 15 different electrode types covering a range of workfunctions. We quantitatively demonstrate that (1) high-workfunction metal electrodes (Au, Pd, Ni) are ideal for high-efficiency inverted device performance; and (2) native metal oxide on metal electrodes (e.g., CuO/Cu, Ag2O/Ag, NiO/Ni), which dramatically reduce conventional device efficiencies, can result in highly efficient inverted BHJ-OPV devices (efficiency of up to 6.7% for the P3HT:PCBM system). This work is an important advance over prior studies as it predicts the electrode materials and configurations that can lead to both high efficiency and high stability BHJ-OPV devices.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solar Energy Materials and Solar Cells - Volume 120, Part B, January 2014, Pages 572–583
نویسندگان
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