کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
78172 49319 2014 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Phase formation in Cu2ZnSnSe4 thin films deposited with multi-stage co-evaporation processes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Phase formation in Cu2ZnSnSe4 thin films deposited with multi-stage co-evaporation processes
چکیده انگلیسی


• Detailed investigation of film growth and phase formation processes during co-evaporation of CZTSe thin films.
• Subdivision of the process in distinct growth phases with characteristic phase formations.
• Chemical reaction between CZTSe and Mo hinders CZTSe growth in the initial stage of the process.

The deposition of Cu2ZnSnSe4 (CZTSe) thin films with a two-stage co-evaporation process was investigated with in situ laser light scattering (LLS) and ex situ characterization methods. As a result of the process conditions as well as intrinsic reactions, the film growth is divided into distinct growth phases with characteristic phase formation processes in each phase. In a first phase, under supply of Cu, Zn, Sn and Se, only Cu2−xSeCu2−xSe and ZnSe are deposited on the substrate. A film with several hundred nanometer thickness is necessary to initiate the CZTSe formation. Then, in a second phase, CZTSe grows by incorporation of Cu and Sn in ZnSe while Cu2−xSeCu2−xSe remains as secondary phase. In the second process stage with terminated Cu evaporation, the remaining Cu2−xSeCu2−xSe is consumed and the film stoichiometry turns from Cu-rich to Cu-poor. A substantial influence on the growth process is found for the Mo substrate, CZTSe growth is hindered by a detrimental interaction between Mo and CZTSe. During the whole process, the Cu2−xSeCu2−xSe phase plays an important role in the grain growth process and supports the formation of large CZTSe grains.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solar Energy Materials and Solar Cells - Volume 120, Part B, January 2014, Pages 596–602
نویسندگان
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