کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7824455 | 1502920 | 2018 | 24 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Critical matters in using Attenuated Total Reflectance Fourier Transform Infrared to characterize the polymer degradation in Styrene-Butadiene-Styrene-modified asphalt binders
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Styrene-Butadiene-Styrene (SBS) polymer is widely employed as an outstanding asphalt modifier. However, inevitable field aging will cause degradation of SBS polymer and consequently shortened pavement lifespan. To characterize the SBS degradation of SBS-modified asphalt (SBSMA), infrared spectroscopy is frequently utilized and the infrared intensity of 966â¯cmâ1 peak is usually employed as an SBS content indicator. However, in this study, Attenuated Total Reflection Fourier Transform Infrared (ATR-FTIR), which is a promising alternative to conventional transmission-FTIR, yielded an abnormal 966â¯cmâ1 peak intensity growth after asphalt aging. To investigate this phenomenon, two types of SBSMAs (radial and linear) were laboratorial aged and their infrared spectra obtained by ART-FTIR and transmission-FTIR were compared. It was found that aging significantly reduced the SBS polymer particle size and facilitated SBS dispersion, and a more uniform SBS dispersion combined with the relatively shallow scanning depth of ATR-FTIR (2â¯Î¼m) caused the different result between ATR-FTIR and transmission-FTIR. A mathematical model was presented to explain this phenomenon. Moreover, a novel infrared index specially developed for ATR-FTIR was proposed to assess the degradation of SBS polymer.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Testing - Volume 70, September 2018, Pages 289-296
Journal: Polymer Testing - Volume 70, September 2018, Pages 289-296
نویسندگان
Chuanqi Yan, Feipeng Xiao, Weidong Huang, Quan Lv,